Arctic sea ice volume on track to reach zero around 2015

The image below shows recent data on Arctic sea ice volume, as calculated using the Pan-Arctic Ice Ocean Modeling and Assimilation System (PIOMAS, Zhang and Rothrock, 2003) developed at the Polar Science Center, Applied Physics Laboratory, University of Washington.

As shown on the images below, by Wipneus and earlier published at the Arctic Sea Ice Blog, sea ice volume loss is on track to reach a minimum of 3000 cubic kilometers this summer.

The recent sea ice volume is in line with the exponential trend calculated by Wipneus that is pointing at zero ice volume around 2015 (image below).

 

As described in an earlier post, I believe that a trendline pointing at 2014 fits the data best (image left).

As discussed, some ice may persist close to Greenland for a few years more, since Greenland constitutes a barrier that holds the sea ice in place. Similarly, natural variability could prolong the ice longer than expected.

However, such arguments offer no reason to rule out an imminent collapse of the sea ice, since natural variability works both ways, it could bring about such a collapse either earlier or later than models indicate.

In fact, the thinner the sea ice gets, the more likely an early collapse is to occur. There is robust evidence that global warming will increase the intensity of extreme weather events, so more heavy winds and more intense storms can be expected to increasingly break up the remaining ice in future, driving the smaller parts out of the Arctic Ocean more easily. Much of the sea ice loss already occurs due to sea ice moving along the edges of Greenland into the Atlantic Ocean.

Could you think of any reason why Arctic sea ice would NOT collapse in 2014?

Methane sequestration in hydrates

Could natural gas should be regarded as "clean energy", or as a "bridge fuel" on the road to a clean energy society? This is questioned by a Cornell University study that concludes that emissions caused by natural gas can be even worse than emissions by coal and diesel oil, especially when looked at over a relatively short period (image below).

Robert Howarth et al. - Methane and the greenhouse-gas footprint of natural gas from shale formations

Not surprisingly, many people call for a ban on drilling in the Arctic, where factors such as remoteness, low temperatures of the water, presence of sea ice, shallowness of seas, long sea currents and lack of bacteria and hydroxyl combine to further increase environmental concerns about spills, leakage and fugitive gases.

Such factors should also make drilling in the Arctic more expensive. At first glance, one would therefore think that over time, in a world shifting to genuinely clean energy such as produced by solar panels and wind turbines, such more expensive "unconventional" sources of fuel will never become economic anyway. Many were therefore caught by surprise when the Energy Department announced the completion of a "successful field trial of methane hydrate production technologies". The announcement adds that a mixture of carbon dioxide and nitrogen was injected to promote the production of natural gas, and that ongoing analyses will be needed to determine the efficiency of simultaneous carbon dioxide storage in the reservoirs.

Indeed, there are concerns about the stability of the sequestered carbon dioxide (i.e. about possible leakage of carbon dioxide over the years), while there are also concerns about emissions caused in the process of producing this carbon dioxide in the first place. A concern voiced by Holly Moeller in a recent post is that any carbon dioxide sequestered as part of the methane extraction process will quickly be replaced through burning of the extracted methane. One should consider that methane in hydrates is highly compressed -- when taken out of the hydrate, it expands some 170 times in volume. And of course, there are also concerns about fugitive releases during capture and leakage during transport and distribution of the methane.

Ironically, environmental concerns can lead both to calls for bans on drilling and to calls for capture of methane in the Arctic. Large amounts of methane are present in undersea sediments in the Arctic. There are indications that much methane is on the verge of abrupt release any time now, due to rising temperatures worsened by the risk of hydrate destabilization due to seismic activity. Some therefore argue that drilling could risk destabilizing the hydrates. Others, on the other hand, argue that to reduce the risks of large methane releases, preemptive action is needed to remove methane from such locations.

In the ANGELS proposal methane is extracted, stored and sold as LNG, for distribution as fuel. There are a number of alternative proposals, each with their advantages and disadvantages. One alternative is to store captured methane in hydrates. Methane hydrates only remain stable within a limited range of  temperatures and pressures, i.e. between 290 and 5,076 psi (2-35 MPa). A group at the University of California - Irvine, led by Prof. Kenneth Yanda, does important research on hydrates. The group proposes to produce hydrates stabilized partly by other gases such as propane, to makes it possible for the hydrates to remain stable at a relatively low pressure of 25 psi (0.172 MPa). Hydrates can be produced that contain larger cages for other gases, as well as smaller cages for occupancy by methane. The group produced propane-methane hydrates that can be stable at temperatures of up to 288 K (14.85 degrees Celsius) and can fill up to 50% of the cages. In other words, such hydrates can store a combination of propane and methane at near ambient temperature and pressure conditions.


Further research is needed, such as into the possibility of converting methane into propane and other gases using UV light. The eventual goal could be long-term storage of such gases in the form of hydrates. In conclusion, rather than using the methane captured in the Arctic as fuel, it could be relocated to places where it can be expected to remain stored long-term, in the form of hydrates, e.g. in the deeper waters north of Alaska.

This may also lead to smart ways of sequestration of carbon removed from the atmosphere. Indeed, when considering places to sequester excess carbon, why not look at where nature stores most carbon, i.e. in hydrates? The amount of carbon stored naturally in hydrates is huge -- the 1992 image below illustrates this well, even though it's dated and estimates have changed a bit since.

The ANGELS proposal

The Arctic Natural Gas Extraction, Liquefaction & Sales (ANGELS) Proposal aims to reduce the threat of large, abrupt releases of methane in the Arctic, by extracting methane from hydrates prone to destabilization.

By Malcolm Light (author), Sam Carana (editor) and Harold Hensel (public relations)

You can view the presentation by clicking on the link below:
docs.google.com/presentation/d/1vOw215pGuiob9q-u0VRrc2Uumfxr8xU3s4Q2k_YNdsE/edit

Project Lucy

Project Lucy is a proposal to decompose methane in the atmosphere using beamed radio frequency transmissions, possibly assisted by further technologies.

By Malcolm Light and Sam Carana

You can view the presentation by clicking on the link below:
docs.google.com/presentation/d/10b1VGrbysjL4GDyQVldwFXtrd7xJgq89XzJNueqVkks/edit

Presentation to the Iowa City Climate Advocates Group

Presentation by Harold Hensel to the Iowa City Climate Advocates Group. This presentation is under construction and will be moved to Shutterfly.com soon.

You can view the presentation by clicking on the link below:
kodakgallery.com/gallery/creativeapps/slideShow/Main.jsp;jsessionid=92F5E56C055A37001FA4BBA859AF8EDE.ecom405_main?sourceId=533754321803&cm_mmc=Share-_-Personal-_-Email-_-Sharee-_-Images&token=655304763507%3A256173328&_requestid=199106

Blowing Hot Air: The Methane Hydrate Delusion

Earlier posted May 10, 2012, at Science 2.0 Seeing Green. Posted with the author's permission.  

By Holly Moeller  

Last week, word came from Prudhoe Bay that sent chills through me as surely as if I’d been standing in the Alaskan North Slope drilling outpost myself. The United States Department of Energy – in collaboration with energy giant ConocoPhillips and the Japanese nationalized minerals corporation – reported success from a month-long test extraction of methane gas tucked into an icy lattice below the permafrost.

These methane hydrates – also called methane clathrates, after the particular crystalline structure of the ice matrix – are found in cold regions (like the Arctic, where low temperatures keep the permafrost soil layer frozen year-round) and off continental shelves (where pressure from a thick blanket of water stabilizes the compressed gas).

Though testing to reveal the full extent and nature of these gas deposits has only just begun, methane hydrates are already making headlines as the next big energy source.

The US Geological Survey estimates that there’s twice as much burnable carbon hiding in hydrates as in all other known fossil fuel deposits worldwide. And since methane gas burns hot and clean – giving off 33% more energy per carbon dioxide molecule emitted as petroleum, without the nasty nitrogen and sulfur oxides that come from coal – ears around the world have perked up.

In 2006, China pledged $100 million to hydrate exploration. In 2008, Japan and Canada completed a six-day test drill in the Mackenzie Basin. And now that this year’s test results are looking good, Secretary of Energy Steven Chu says that domestic gas prices could drop 30% by 2025.

As an added bonus, methane extraction traps CO2. The latest technology pumps the most notorious greenhouse gas into the ground, where it replaces methane in the ice matrix. The displaced methane is then pumped to the surface and – in the DoE’s (and, undoubtedly, ConocoPhillips’) vision – down pipelines to heat homes in the Lower 48.

Plus, argue supporters, climate change projections indicate that rising temperatures may release much of that methane anyway. If the permafrost thaws or the ocean warms, vast tracts of icy clathrates could melt, outgassing methane – which has 20 times the warming potential of CO2 – into the atmosphere, further accelerating climate change. This is one of the most feared positive feedback loops known to climate scientists.

So wouldn’t it be nice if we could turn some of that methane into carbon dioxide ahead of time?

I don’t think so.

Burning fossil fuels – oil, coal, and natural gas – put us into our tenuous climatic position in the first place. Any CO2 we sequester during methane hydrate extraction will quickly be replaced through burning of the extracted methane. And the CO2 trap is only temporary: warmer polar temperatures will free it as surely as the presently trapped methane scientists are so concerned about.

Add to this the issue of scale. Given that commercialization of methane hydrate extraction is still a political pipe dream, we’re unlikely to process any significant portion of the 320 quadrillion cubic feet of methane scattered in hydrates around the country.

Now to don our economic hats. Increased supply and decreased costs only drive up demand. Say we can, as the DoE promises, double our natural gas supply and effect dramatic price cuts by using only 1% of domestically available methane hydrates. This quick fix of another carbon-based fuel will only delay our ultimate sustainability reckoning.

Methane hydrates, no matter how vast their supply seems, are just another nonrenewable resource. A boom in gas production will add years – maybe decades – to the difficult but necessary transition to renewable energy sources. And in the meantime, we’ll be doing plenty of damage to our environment both globally – through additional greenhouse gas emissions – and locally – by drilling in sensitive ecosystems.

In the last decade, we’ve fought plenty of environmental battles over how and where to drill for oil. We’ve seen the consequences – Deepwater Horizon and the Gulf of Mexico 2010 spill, for example – of pushing our technological limits towards harder and harder to reach deposits.

And now we want to grasp at something even more risky, at mineral formations that, when destabilized, cause explosions and landslides.

I’m afraid that the laws of economics – especially in a country that will invest $6.5 million this year alone (plus an additional $5 million, pending Congressional approval) on methane hydrate recover research – will once again favor Sarah Palin’s mantra, “Drill, baby, drill.” Because as surely as methane is trapped within its lattice of ice, we’ve trapped ourselves in a spiderweb of fossil fuel dependency. Unlike methane, however, it seems even climate change can’t force us out.

Editor's notes:  
- Methane's global warming potential (GWP) is more than 130 times that of carbon dioxide over a period of ten years, as described in the post Methane in the Arctic.
- The Energy Department's announcement can be viewed at: http://energy.gov/articles/us-and-japan-complete-successful-field-trial-methane-hydrate-production-technologies

Proposal to extract, store and sell Arctic methane

A Proposal for the Prevention of

Arctic Methane Induced Catastrophic

Global Climate Change by Extraction

of Methane from beneath the Permafrost/

Arctic Methane Hydrates and its Storage and

Sale as a Subsidized "Green Gas"

Energy Source

By Malcolm P.R. Light

PhD. UCL
May 27th, 2012

DEDICATION

This proposal is dedicated to my Father and Mother, Ivan and Avril Light,

both meteorologists and farmers who knew about the vagaries of the weather;

and to all our grandchildren whose entire future depends on its successful outcome.

EXECUTIVE SUMMARY

Methane hydrates (clathrates) exist on the Arctic submarine shelf and slope where they are stabilized by the low temperatures and they have a continuous cap of frozen permafrost which normally prevents methane escape (Figure 1 below).

However, recent research has shown that millions of tons of methane are already being released in the Siberian Arctic through perforated zones in the subsea permafrost cap with the concentrations reaching up to 100 times the normal, such as in the discharge region of the Lena River and the junction of the Laptev and East Siberian Seas (Shakova et al. 2010).

Mean methane concentrations in the Arctic atmosphere showed a striking anomalous buildup between November 1-10, 2008 and November 1-10, 2011 (Figure 2 above)(Yurganov 2012 in Carana, 2012a).

The surface temperature hotspots in the Arctic caused by global warming correlate well with the anomalous buildups of atmospheric methane in the Arctic (Figure 3 right, in Arctic feedbacks in Carana, 2012a).

This indicates that there is a strong correlation between the dissociation of Arctic subsea methane hydrates from the effects of globally warmed seawater and the increasing size and rate of eruptions of methane into the Arctic atmosphere.

• Methane eruption zones (torches) occur widely in the East Siberian Arctic Shelf (ESAS) (Shakova et al., 2008; 2010), but the largest and most extreme are confined to the region outside the ESAS where the Gakkel "mid ocean" ridge system intersects at right angles the methane hydrate rich shelf slope region (Figure 9 above and Figure 17 right). 
  
  The wedge-like opening and spreading of the Gakkel Ridge is putting the formations and overlying methane hydrate sediments under torsional stress and in the process activating the major strike slip faults that fan away and thrust faults that radiate from this region (Figure 16 below). 
  
  Light and Solana (2002) predicted that the north slope of the Barents - Laptev - East Siberian seas at the intersection of the slowly opening Gakkel Ridge. This region would be especially vulnerable to slope failures where unstable methane hydrate would be affected by seismicity from earthquakes with magnitudes greater then 3.5 Richter and at depths of less than 30 km. Many earthquakes occur along the Gakkel Ridge often with magnitudes greater than 4 to 6 and at depths shallower than 10 km (Avetisov, 2008) continuously destabilizing the already unstable methane hydrates there (Figure 16 below). 

• Major and minor strike slip and normal faults form a continuous subterranean network around the Gakkel Ridge and are clearly charged with overpressured methane because methane gas is escaping from these fault lines many hundreds of km up dip and away from the subsea methane hydrate zones through which these fault zones pass (Figures 9 above and Figure 18 right).
   
• One small methane eruption zone occurs directly over the centre of the Gakkel Ridge and probably represents thermogenic deep seated methane being released by the magmatic heating of adjacent oil/gas fields by rising (pyroclastic) magma (Figure 9 above)(Edwards et al. 2001). This surface gas eruption appears to only represent a tiny percentage of the total gas released from other sources such as methane hydrates, as do methane eruptions around Cenozoic volcanics offshore Tiksi on the East Siberian shelf (Figure 11 right and Figure 16 above).
  
  
• An elongated set of methane eruption zones occur on the submarine slope north of Svalbard flanking the Gakkel Ridge and result from methane hydrate decomposition caused by sudden changes in pressure and temperature conditions due to submarine slides/slumps (Figure 9 above). These submarine slides/slumps were evidently set off by seismic activity along the Gakkel Ridge which lies a short distance to the north in an area where the ridge opening is the widest (Figure 16 above). This may be similar to the Storegga slide (Light and Solana, 2002; NGI, 2012). Light and Solana (2002) predicted that the western slopes of Norway and along the Barents Sea to Svalbard, would be especially vulnerable to slope failures in regions of unstable methane hydrate. Here the slowly spreading Gakkel Ridge runs as close as 30 km to the slope. Earthquake activity along the Gakkel Ridge often has magnitudes greater than 4 to 6 at depths shallower than 10 km (Avetisov, 2008) and will also be destabilizing the already unstable methane hydrates here leading to eruptions of methane into the atmosphere (Figure 9 above and Figure 16 above).

There are some 1000 Gt to 1400 Gt (10^9 tonnes) of carbon contained in the methane hydrates on the East Siberian Arctic Shelf and 700 Gt of free methane is trapped under the Arctic submarine permafrost (Shakova et al. 2008, 2010). Shakova et al. estimate that between 5% to 10% of the subsea permafrost (methane hydrates) in that region is now punctured allowing methane to escape at a rate of about 0.5 Mt (500,000 tonnes) a year and that up to 50 Gt (10^9 tonnes) could be released abruptly at any time soon. Release of this subsea Arctic methane would increase the worldwide atmospheric methane content about 12 times equivalent to doubling the carbon dioxide content of the atmosphere. This "methane hydrate gun", which is cocked and ready to fire at any moment, is an extremely serious scenario that will cause abrupt climate change (CCSP, 2008; IMPACTS 2008). Even if this subsea volume of Arctic methane is released over a longer interval of some ten to twenty years it will still result in a massive feedback on global warming and drive the Earth on an irretrievable plunge into total extinction.

Figure 5. From: Carana 2012b, originally from: arctische pinguin - click to enlarge

After 2015, when the Arctic Ocean becomes navigable (Figure 5 above, Carana 2012b) it will be possible to set up a whole series of drilling platforms adjacent to, but at least 1 km away from the high volume methane eruption zones and to directionally drill inclined wells down to intersect the free methane below the sealing methane hydrate permafrost cap within the underlying fault network (Figure 18 above).

High volume methane extraction from below the subsea methane hydrates using directional drilling from platforms situated in the stable areas between the talik/fault zones will reverse the methane and seawater flow in the taliks and shut down the uncontrolled methane sea water eruptions (Figure18 above). The controlled access of globally warmed sea water drawn down through the taliks to the base of the methane hydrate - permafrost cap will gradually destabilize the underlying methane hydrate and allows complete extraction of all the gas from the methane hydrate reserve (Figure18 above). The methane extraction boreholes can be progressively opened at shallower and shallower levels as the subterranean methane hydrate decomposes allowing the complete extraction of the sub permafrost reserve (Figure18 above).

The methane and seawater will be produced to the surface where the separated methane will be processed in Floating Liquefied Natural Gas (FLNG) facilities and stored in LNG tankers for sale to customers as a subsidised green alternative to coal and oil for power generation, air and ground transport, for home heating and cooking and the manufacture of hydrogen, fertilizers, fabrics, glass, steel, plastics, paint and other products.

Where the trapped methane is sufficiently geopressured within the fault system network underlying the Arctic subsea permafrost and is partially dissolved in the water (Light, 1985; Tyler, Light and Ewing, 1984; Ewing, Light and Tyler, 1984) it may be possible to coproduce it with the seawater which would then be disposed of after the methane had be separated from it for storage (Jackson, Light and Ayers, 1987; Anderson et al., 1984; Randolph and Rogers, 1984; Chesney et al., 1982).

Many methane eruption zones occur along the narrow fault bound channels separating the complex island archipelago of Arctic Canada (Figure 6 and 9). In these regions drilling rigs could be located on shore or offshore and drill inclined wells to intersect the free methane zones at depth beneath the methane hydrates, while the atmospheric methane clouds could be partly eliminated by using a beamed interfering radio transmission system (Lucy Project) (Light 2011a). A similar set of onshore drilling rigs could tap subpermafrost methane along the east coast of Novaya Zemlya (Figure 6 below and 9 above).

Methane is a high energy fuel, with more energy than other comparable fossil fuels (Wales 2012). As a liquid natural gas it can be used for aircraft and road transport and rocket fuel and produces little pollution compared to coal, gasoline and other hydrocarbon fuels.

Support should be sought from the United nations, World Bank, national governments and other interested parties for a subsidy (such as a tax rebate) of some 5% to 15% of the market price on Arctic permafrost methane and its derivatives to make it the most attractive LNG for sale compared to LNG from other sources. This will guarantee that all the Arctic gas recovered from the Arctic methane hydrate reservoirs and stockpiled, will immediately be sold to consumers and converted into safer byproducts. This will also act as an incentive to oil companies to produce methane in large quantities from the Arctic methane hydrate reserves. In this way the Arctic methane hydrate reservoirs will be continuously reduced in a safe controlled way over the next 200 to 300 years supplying an abundant "Green LNG" energy source to humanity.